This seems to be the first instance of Charlie Brown pitching. I can forgive the umpire sitting behind the pitcher for the chance to see Snoopy, in one of his earliest fully-intelligent moments, declaring a ball to CB's consernation. A funny strip!
Schroeder is the default baby character again here, filling in the same kind of role that would later be filled, in turn, by Lucy, Linus, then Sally. These kinds of baby jokes would decrease in number over time, presumably as Schulz's own connection with infants (such as his own young kids) diminished over time. I barely remember seeing much of Rerun's infanthood, he just sort of settled into being the preschool character.
It's the first time the characters have appeared in silhouette.
One measure of the quality of a comic character's design is how recognizable is its outline. It's easy to tell Charlie Brown apart from Patty here in panel three. (John Kricfalusi had a blog post about this a little while back, but I can't find it at the moment.)